Fortune will stream select sessions from its Fortune Most Powerful Women Summit for the first time ever.

The Fortune Most Powerful Women Summit will be held at the Mandarin Oriental Hotel in Washington, D.C., Oct. 4-6, and confirmed speakers include Secretary of State Hillary Rodham Clinton, Berkshire Hathaway chairman and CEO Warren Buffett, CNBC anchor Maria Bartiromo, Yahoo! CEO Carol Bartz, Demand Media chief revenue officer Joanne Bradford, former CNN and NBC anchor Campbell Brown, MSNBC Morning Joe co-host Mika Brzezinski, CNN chief political correspondent Candy Crowley, Fortune senior editor Nina Easton, Fortune assistant managing editor Leigh Gallagher, TIME executive editor Nancy Gibbs, Fortune senior writer Jessi Hempel, Blip.tv co-founder Dina Kaplan, Oxygen Media founder Geraldine Laybourne, Facebook vice president for global public policy Marne Levine, Fortune senior editor at large Carol Loomis, ImpreMedia CEO Monica Lozano, Fortune executive editor Stephanie Mehta, Paley Center for Media president and CEO Patricia Mitchell, Time Inc. chairman Ann Moore, TIME Washington correspondent Jay Newton-Small, CNBC Squawk Box co-anchor and Fortune guest columnist Becky Quick, Fortune senior editor Jennifer Reingold, Facebook chief operating officer Sheryl Sandberg, Fortune editor at large Pattie Sellers, NBC News chief medical editor Nancy Snyderman, Washington Post national political correspondent Karen Tumulty, Real Simple managing editor Kristin van Ogtrop, and Fox News Channel On the Record with Greta Van Susteren host Greta Van Susteren.